Despite the abundance of silicons in the Earth's crust, not all minerals contain silicon. The atoms of many metals, which tend to lose electrons and become positively charged, like to bond with other atoms or groups of atoms that tend to gain atoms and become negatively charged. For example, atoms of sodium, a metal, and chlorine, a non-metal, pair up in equal numbers to form sodium chloride, also known as halite (or common table salt). Other important types of non-silicate minerals include carbonates, with metals bonded to groups of carbon and oxygen atoms; oxides, with metals joined to oxygen alone; sulfides, which consist of metal and sulfur atoms; and sulfates, in which groups of sulfur and oxygen atoms are joined with metal atoms.

Minerals can be opaque, meaning they block all light from passing through them; translucent, meaning they block some of the light; or transparent, meaning they pass most or all the light. A typical garnet or amethyst crystal is translucent; if you hold it up to a bright light, only a small fraction of the light entering the crystal ever reaches your eye, and you cannot see clear images through the crystal. Mica, a silicate mineral, can be cut into thin sheets so transparent that they serve as panes of a window. One colorless, transparent variety of calcite, dubbed "Iceland spar," exhibits a phenomenon called double refraction, which makes one object look like two. Another mineral, a borate called ulexite, occurs in thin parallel fibers that conduct light through them by total internal reflection, just like manufactured optical fibers. Ulexite seems to project an image onto the polished surface of the mineral, giving it the nickname "television stone."

Gemstones are minerals that are cut and polished to make beautiful "stones" for jewelry and other adornments. Humans traditionally consider diamonds, rubies, sapphires, and emeralds to be the four "precious" gemstones, with all other gemstones called "semiprecious." Many gems are transparent, meaning they allow some or most of the incident light to pass through them. To make a stone sparkle, gemcutters cut and polish the facets, or flat outer surfaces, of a gemstone to boost the number of times a light beam will reflect internally before leaving the stone and reaching the eye. Some semiprecious stones, such as malachite and lapis lazuli (a rock containing the mineral lazurite), are opaque to light; gemcutters polish them to a high gloss, without facets. This shiny, rounded type of gemstone is called a cabochon. Corundum (ruby or sapphire) specimens that contain tiny fibers of other minerals also may be cut into cabochons to create a luminous "star" effect on the stone's surface.